To steam or not to steam...I did not steam mine, nor do I think it will be necessary looking at the curves on your canoe. Ash will bend easier than oak, and is slightly lighter and almost as strong. As far as weight, I don't think that 3/4 x 3/4 piece will make all that much difference. My canoe is almost 19 foot long, so I used a 10 footer that I riped down and joined in the middle. I secured the middle with clamps, then screws, then step by step, using all my clamps worked my way out to each end (a little bit one way, then the other.)
Even if you treat your canoe with a decent amount of care, softwood will take a beating if you car top it. And even if you save a couple of pounds, are you going to notice the difference in gunwale wood weight with the whole canoe on your shoulders?
Great find you got there!
Chuck