I agree with Dave totally on this, not enough draft. My bro in law has done several molds for me over the years (owns a fab shop) and now that he is aware of this issue, he no longer does them at 90 degrees.
that said, on the old mold, I just used a file, first rubbed the file with chalk, (think kids sidewalk chalk) then slowly filed the sides just slightly. I then would clean out the file after about 50 strokes or so with a brass wire brush, re load chalk (trying to keep the soft alum from filling/cloggin the file) Took a bit to put a bit of chamfer on the sides, but not bad. About 2 beers worth. I would also say 5 degrees is really more than plenty, mine have about 2-3 degrees at the most and have no issues. I have never had to "smoke" the molds, but I have heard that helps as well. I would not try to get a router running, unless you really know how to use one, and have the proper hold downs available, that said, it woudl work but very risky. VERY light passes to just shave off material. file is safer and actually quicker with less set up time.
filing will keep your buddy out of trouble too!!
best of luck with any method