Vinegar for Epoxy residue "clean-up" on tools, etc.

I have been building wood and epoxy boats for 35 years, have seen lots of sensitivity issues among our workers. If you get the "Rash" find a different job, your body is telling you something! We have done a lot of research on this. and found out that it is not the resin that's toxic, but the hardner. My guys wash up with that gritty orange hand soap they sell in the auto parts stores. Most other clean up jobs are done with denatured alcohol. Acetone is for polyester. Rich
Yes, the anecdotal evidence suggest that the amine hardener, as well as some creative "stuff" used in production of the hardener in the early days of epoxy resin production, cause the reaction. Additional evidence points to acetone as the carrier compound that helps the hardener solution penetrate skin membranes. I strongly suspect that, a lot of these cases were a consequence of epoxy users "bathing" in acetone washes to compensate for the fast evaporation rate due to its low BP,but obviously there is no way to stratify volume of acetone use per worker or shop with frequency of contact dermatitis retrospectively.

Over your thirty-five years of boat building, I am sure you are also aware that formulations of hardener have evolved to employ amine compounds that are "cleaner" and potentially offer lower hypersensitivity rates on chronic exposure.
 
You can get to Toxnet via the NIH's website to enter the National Library of Medicine to examine health impacts of a variety of compounds...
The Danes require mandatory epoxy safety and handling exposure training for workers undergoing routine exposure in the workplace. They also are quite organized in their ability to track the effectiveness of the implementation of these requirements:
http://toxnet.nlm.nih.gov/...2/f?./temp/~5XIM5q:1

I couldn't find any data on inhalation risks from sanding uncured expoxy resin without adequate respirator use.

There is a companion study in Hazmap that reports the development of skin hypersensitiy to epoxy resin is largely a cosequence of disphenol-A and epichlorohydrin exposure in 90% of the cases, with the remaining 10% attributed to the hardener component. So much for anecdotal reports...

http://hazmap.nlm.nih.gov/...ytblagents&id=30
 
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